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A F )actual × 100 ( A F )stoichiometric ENTROPY ds = (1/T) δQrev ( A F )actual − ( A F )stoichiometric × 100 ( A F )stoichiometric Inequality of Clausius ò (1/T ) δQrev ≤ 0 Percent Theoretical Air = Percent Excess Air = pi s2 – s1 = ò12 (1/T) δQrev ò12 (1/T) δQ ≤ s2 – s1 SECOND LAW OF THERMODYNAMICS Thermal Energy Reservoirs Isothermal, Reversible Process ∆s = s2 – s1 = Q/T ∆Sreservoir = Q/Treservoir , where Q is measured with respect to the reservoir. Isentropic process ∆s = 0; ds = 0 Kelvin-Planck Statement of Second Law No heat engine can operate in a cycle while transferring heat with a single heat reservoir.
At the point of impending motion, U1 + T1 = U2 + T2. F = µs N If nonconservative forces are present, then the work done by these forces must be accounted for. When motion is present F = µk N, where U1 + T1 + W1→2 = U2 + T2 (Care must be exercised during computations to correctly compute the algebraic sign of the work term). µk = Impact Momentum is conserved while energy may or may not be conserved. For direct central impact with no external forces Belt friction is discussed in the STATICS section.
Liquid hf Evap. hfg Entropy kJ/(kg·K) Sat. vapor hg Sat. liquid sf Evap. sfg Sat.